Hexakis(dimethyl sulfoxide-κO)thallium(III) trinitrate

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Hexakis(dimethyl sulfoxide-κO)cobalt(III) trinitrate

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Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate

The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol-ecules coordinated to a Tl(III) atom, which lies on a axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa-hedral, defined by six O atoms of the DMSO mol-ecules. In the crystal structure, C-H⋯O hydrogen bonds are observed....

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In the title compound, C9H26N3 (3+)·3NO3 (-), the triprotonated 1,1,4,7,7-penta-methyl-diethylenetri-amine mol-ecules are linked to the nitrate anions by multiple bifurcated N-H⋯(O,O) and weak C-H⋯O hydrogen bonds. The organic cation is characterized by N-C-C-N torsion angles of -176.2 (2) and 176.6 (2)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810022646